Table 5: Kinetic and thermodynamic parameters data of the metal complexes 1–6.
Compound | Step | Temp. range (°C) | E* (kJ.mol−1) | A (S−1) | ΔS* (JK−1.mol−1) | ΔH* (kJ.mol−1) | ΔG* (kJ.mol−1) |
1 | 1 | 250–330 | 141.557 | 1.23442E+12 | −234.19 | 136.534 | 277.887 |
[Cr(CO)4ML] | 2 | 330–450 | 116.684 | 132830241.1 | −236.66 | 111.116 | 269.50 |
2 | 1 | 130–180 | 197.467 | 1.40428E+23 | −228.69 | 193.851 | 293.261 |
[Mo(CO)4ML] | 2 | 180–435 | 20.874 | 759103782.8 | −251.44 | 14.976 | 193.222 |
3 | 1 | 131–280 | 64.90 | 8.455E+05 | −134.95 | 61.13 | 122.26 |
[W(CO)4ML] | 2 | 282–350 | 135.13 | 1.807E+11 | −33.86 | 130.89 | 148.13 |
3 | 350–589 | 46.73 | 5.413E+07 | −103.04 | 41.53 | 105.93 | |
4 | 1 | 131–395 | 31.00 | 5.670E+07 | −99.41 | 27.48 | 69.54 |
[Cr(CO)4FL] | 2 | 399–509 | 158.93 | 3.689E+10 | −49.59 | 153.20 | 187.36 |
5 | 1 | 140–233 | 132.64 | 1.429E+14 | 22.42 | 128.78 | 118.41 |
[Mo(CO)4FL] | 2 | 233–431 | 49.61 | 2.622E+06 | −127.49 | 44.84 | 117.89 |
6 | 1 | 141–336 | 43.5 | 1.950E+06 | −129.65 | 38.9 | 110.6 |
[W(CO)4FL] | 2 | 338–598 | 43.89 | 4.671E+07 | −104.55 | 38.50 | 106.21 |