Catalytic Potential of Mononuclear Cr(III)-Imine Complexes for Selective Oxidation of Benzyl Alcohol by Aqueous H<sub>2</sub>O<sub>2</sub>: Table 3

Table 3: Thermal decomposition steps, mass loss (%), proposed lost segments, final residue thermo-kinetic activation parameters of each decomposition step for the prepared complexes.


Comp.	Decomp. temp. (°C)	Mass loss (%)		Proposed segment	E^* (KJmol⁻¹)	A(S⁻¹)	ΔH^* (KJmol⁻¹)	ΔG^* (KJmol⁻¹)	ΔS^* (Jmol⁻¹ K⁻¹)
		Found	Calc.

CrLA1	35–110	8.12	8.05	2H₂O	78.3	0.096	77.8	93.6	−251.55
	112–211	8.22	8.05	2H₂O			78.3	119.7	−259.52
	213–285	13.78	13.87	NO₃			76	141.7	−262.97
	287–399	31.65	31.77	C₁₀H₆O			75.5	165.8	−265.5
	401–567	26.52	26.60	C₇H₅NO			74.2	205.8	−268.57

Residue	> 567	11.70	11.63	Cr			—	—	—