Table 3: Important optimized bond lengths (Å) and bond angles (°) of [Sn(C4H9)2LCl].
| Complex (Å) | L | Complex (Å) | ||
| Sn-O1 | 1.777 | Sn-C17 | — | 2.163 |
| Sn-N1 | 2.379 | |||
| Sn-N2 | 2.296 | N1••••O1 | 2.656 | 2.643 |
| Sn-Cl | 2.684 | N1••••N2 | 2.944 | 2.647 |
| Sn-C16 | 2.179 | N2••••O1 | 5.532 | 4.178 |
| Complex (°) | Complex (°) | |||
| N1-Sn-N2 | 68.94 | C16-Sn-O1 | 94.55 | |
| N1-Sn-O1 | 79.01 | C16-Sn-N1 | 88.21 | |
| O1-Sn-C17 | 99.62 | C16-Sn-N2 | 87.86 | |
| N2-Sn-C17 | 109.6 | C16-Sn-C17 | 110.3 | |
| Cl-Sn-O1 | 89.44 | O1-Sn-N2 | 147.8 | |
| Cl-Sn-N1 | 73.45 | Cl-Sn-C16 | 160.2 | |
| Cl-Sn-N2 | 78.62 | N1-Sn-C17 | 161.4 | |
| Cl-Sn-C17 | 88.02 | O1-N1-N2-C17 | +8.469∗ | |
| ∗Dihedral angle. | ||||